Amosite Condenser Central Stop Dispersion Staining
The D-line refractive index along the length of this sample
of amosite asbestos is about 1.706. It matches the
refractive index of the Cargille High Dispersion 1.680 liquid at a wavelength of
about 440 nanometers. At this
wavelength the Cargille liquid has a refractive index of about 1.723, as does the
amosite. This Type of Dispersion
Staining produces a single color for any given wavelength match between a given
liquid and solid with a fixed single
linear polarizing filter. Oblique condenser darkfield dispersion staining produces
the same colors as objective cental
stop dispersion staining but the particles are in much better focus. As a result it
is easier to see the particles that
are producing the effect.
Transmitted Condenser Central Stop with one linear Polarizing Filter Oriented Parallel
to the Fiber Length
Definition/Function:
Glass fiber is a fiber composed of a material in a "glassy" state. A "glass" is any of a
large class of materials that
solidify from a molten state without crystallization and with random molecular
orientation. They are regarded physically
as supercooled liquids rather than true solids (based on the definition in the AMERICAN
HERITAGE DICTIONARY). Chemically
they generally contain silicon along with a number of other elements though carbon-based
glasses are also common in some
environments. It is estimated that there are in excess of 50,000 different chemical
compositions for glass (MATERIALS
HANDBOOK, by George S. Brady and Henry R. Clauser). Glass is easily formed at elevated
temperature and can be made into
fibers intentionally, as an artifact of thermal forming, or as a natural process as in
the case of volcanic glass fiber
(Pele's Hair).
"Glass fiber", as identified by light microscopy, is defined by its morphology and a few
optical properties. Its
cylindrical shape (a result of surface tension at elevated temperature) is best seen by
the relief gradient at
the edge of the fiber when viewed with transmitted oblique illumination. The random
molecular structure is demonstrated by
the fact that the fiber is isotropic (disapears in all orientations when viewed between
linear polarizing filters at 90
degrees to one another). The brittle nature of the fiber is shown by the lack of plastic
deformation at the terminations
of the fiber.
Glass fiber from acoustic ceiling tile is identified by the binders and fillers stuck to
the outside of the fiber and the
lack of impacted debris adhering to the fibers. Ceiling tile is a molded material and
the molding process imposes
certain compositional demands and limitations. A binder must be present in sufficient
quantity to impart some rigidity to
the tile. The binder is relatively expensive so it is often extended by adding mineral
fillers. Flexible fibers, such as
paper fiber or plastic fiber, may be added to impart greater durability to the tile. The
presence of these materials
physically attached to the glass fiber identifies the fiber as being from acoustic
ceiling tile. The type of acoustic
ceiling tile is identified by the composition of the attached materials.
Amosite asbestos is the fibrous form of amphibole in the cummingtonite-grunerite family.
Its chemical composition is
(Mg, Fe, Mn)7[Si8O22](OH) 2. It is the next
most common commercial asbestos
after Chrysotile.
Significance in the Environment:
Glass fiber on surfaces has been associated with a number of health complaints and with
the "Sick Building Syndrome" in
general. This is not true of glass fiber collected in air samples. The reason for this
seems to be that in most cases
in offices, schools, and homes the transport to the upper respiratory system is the
result of mechanical disturbance and
transport from contaminated surfaces and not from elevated airborne loading (see
references in the microlabnw paper cited
below).
Amosite is a hazardous material and exposure should be very carefully limited. It is one
of the more hazardous of the
asbestos minerals. Exposure to asbestos fiber will not result in health symptoms
associated with the work place early in
the exposure. There are no early symptoms of the onset of asbestos related
disease.
Amosite asbestos was used primarily for boiler and steam pipe insulation and for sound
proofing products like acoustic
ceiling tile. It is not a common form of amphibole and so its presence in the
environment generally indicates the
disturbance of an asbestos containing construction material.
Characteristic Features:
Glass fiber may be distinguished from bird feather barbules by the low birefringence of
the barbules and by accessory
structures (nodes) on the barbules, if present.
Glass fiber may be distinguished from silaceous phytoliths by accessory structures on
the phytoliths, the low refractive
index of the phytoliths (less than 1.500), by surface texture on the phytoliths, or by
the non-cylindrical shape of the
phytolith. These properties exclude most silaceous phytoliths from confusion with glass
fiber unless a lower refractive
index glass fiber is present, such as fused quartz (refractive index of 1.48).
Amosite fibers tend to be straight and are rather stiff. The fibers tend to be bundles
and the terminations are often
Well broomed. They show good dispersion colors when dispersion staining is used and they
are mounted in a high dispersion
1.680 refractive index oil.
Associated Particles:
The source of glass fiber in an environment is identified by the types of materials
associated with the glass fiber.
Chemical composition is often unreliable because of variations in the chemical
composition of the glass itself and because
of surface films or particle adhering to the fiber that alter its chemical signature.
Binders and the fillers, extenders,
and pigments that may be associated with the binders attached to the fiber are a good
indication of the fibers source. In
addition to the binder there are often other fiber types attached to the glass fiber by
the binder that further clarify the
source of the glass fiber.
The two most common non-fibrous materials that amosite is associated with are magnesia
and gypsum. A very common block
form of insulation containing amosite was simply designated as Magnesia 80. It is 80%
magnesia (magnesium oxide) and 20%
asbestos. The asbestos content ranges from 20% amosite to various blends of amosite and
chrysotile. The gypsum
formulation was similar though often calcite (limestone) would be blended into the
gypsum.
When used in acoustic ceiling tile it is generally mixed with glass fiber and an epoxy
binder.
References:
1. Asbestos Textile Institute, HANDBOOK OF ASBESTOS TEXTILES, 3RD EDITION, 1967.
2. Campbell, W.J., R.L. Blake, L.L. Brown, E.E. Cather, and J.J. Sjoberg, IC 8751;
SELECTED SILICATE MINERALS AND THEIR ASBESTIFORM VARIETIES, US Dept. of the Interior,
Bureau of Mines Information Circular, 1977
3. Deer, W. A., R. A. Howie, and J. Zussman, AN INTRODCUTION TO THE ROCK-FORMING
MINERALS, ISBN 0-582-30094-0, pp. 22-6, 1992
4. Ledoux, R. L. (ed), SHORT COURSE IN MINERALOGICAL TECHNIQUES OF ASBESTOS
DETERMINATION, Mineralogical Association of Canada, 1979.
5. Levadie, Benjamin (ed), DEFINITIONS FOR ASBESTOS AND OTHER HEALTH-RELATED SILICATES,
ASTM STP 834, 1984.
6. Riordon, P. H. (ed), GEOLOGY OF ASBESTOS DEPOSITS, Society of Mining Engineers, 1981.
7. World Health Organization, ASBESTOS AND OTHER NATURAL MINERAL FIBRES, Environmental
Health Criteria 53, 1986.
8. Brady, George S. and Henry R. Clauser, MATERIALS HANDBOOK, 11th Edition, ISBN
0-07-007069-5, pp. 341-350
9. http://www.microlabnw.com/index/Glass%20Fiber%20and%20Health%20Complaints.pdf
10. Parker, Sybil P. (ed), McGRAW-HILL ENCYCOPEDIA OF PHYSICS, ISBN 0-07-045253-9,
p.27.