Pleochroism of Crocidolite
Crocidolite appears distinctly blue when a single linear
polarizing filter is oriented perpendicular to the fibers.
Transmitted Crossed Linear Polarized Light Illumination
Definition/Function:
Crocidolite asbestos, the blue asbestos, is a fibrous amphibole with the chemical
composition
Na2Fe 5[Si8O22](OH) 2. It is one
of the more hazardous asbestos
minerals.
Significance in the Environment:
Crocidolite is the third most common commercial asbestos, behind Chrysotile and Amosite.
It is used in the blue ceramic
water pipe that was used widely in the past. It was commonly used in high temperature
environments, like boiler. It is
the only asbestos other than chrysotile that can be easily woven into cloth. It is rare
as a natural mineral so when it
is found in an environment it is usually the result of the degradation of an asbestos
containing construction material.
Characteristic Features:
The blue color of Crocidolite is unique in the asbestos minerals though there are some
other blue or blue-green mineral
fibers. It has relatively high refractive indices, around 1.705. It has a dispersion of
the birefringence that is
visible in thin fibers. For these thin fibers they appear pink between crossed
polarizers. For thicker fibers the blue
absorbs most of the red end of the spectrum and the fibers appear blue. This is a very
characteristic feature.
Associated Particles:
Crocidolite is often used with Chrysotile asbestos.
References:
1. Asbestos Textile Institute, HANDBOOK OF ASBESTOS TEXTILES, 3RD EDITION, 1967.
2. Campbell, W.J., R.L. Blake, L.L. Brown, E.E. Cather, and J.J. Sjoberg, IC 8751;
SELECTED SILICATE MINERALS AND THEIR ASBESTIFORM VARIETIES, US Dept. of the Interior,
Bureau of Mines Information Circular, 1977
3. Deer, W. A., R. A. Howie, and J. Zussman, AN INTRODCUTION TO THE ROCK-FORMING
MINERALS, ISBN 0-582-30094-0, pp. 261-267, 1992
4. Ledoux, R. L. (ed), SHORT COURSE IN MINERALOGICAL TECHNIQUES OF ASBESTOS
DETERMINATION, Mineralogical Association of Canada, 1979.
5. Levadie, Benjamin (ed), DEFINITIONS FOR ASBESTOS AND OTHER HEALTH-RELATED SILICATES,
ASTM STP 834, 1984.
6. Riordon, P. H. (ed), GEOLOGY OF ASBESTOS DEPOSITS, Society of Mining Engineers, 1981.
7. World Health Organization, ASBESTOS AND OTHER NATURAL MINERAL FIBRES, Environmental
Health Criteria 53, 1986.