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Potassium Uranyl Acetate Crystals

Potassium Uranyl Acetate

These lath crystals form if potassium is present in a powder added to a uranyl acetate solution.

Transmitted Circular Polarized Light

Definition/Function:

These are characteristic crystals of K(C2H3O2)-A standard test for potassium is to test the dry salt with a solution of uranyl acetate (UO2(C2H3O2)-2H2O) in water made acid with a little acetic acid. If potassium ions are present well in excess of any divalent ions then these typical crystals are evident. If these crystals form then potassium is present. If these crystals don't form then potassium ions are not present or they are part of a complex crystal structure that may not be unique. Extraction of the interfering elements may be required.

Significance in the Environment:

Characteristic Features:

Potassium Uranyl acetate has a relatively high refractive index and is birefringent.

Associated Particles:

A number of other crystalline or non-crystalline phases may be present. A summary of the elements that may cause these other precipitates is given on page 57 and 58 of Chamot and Mason.

References:

Chamot, Emile Monnin and Clyde Walter Mason, HANDBOOK OF CHEMICAL MICROSCOPY, Volume II, pp. 51-58, 1940.